Surface enhanced Raman scattering (SERS) has emerged as an ultrasensitive analytical tool for chemical, biological, and medical analysis. SERS spectra of permethrin, a common synthetic pyrethroid, were investigated for the first time. The SERS substrates used in this work were a silver nanofilm (AgNF) deposited on glass chips. The characteristic SERS bands of permethrin were analyzed and assigned to the corresponding modes. The strongest SERS band appeared at 1003 cm-1 due to the breath vibration of benzene ring in the permethrin molecule. A detection limit of 10 ppm was obtained on the AgNF sub-strates. A good linear relationship between peak height of the 1003 cm-1 band and permethrin concentration was observed in the range of 10 – 1000 ppm. The results obtained in this work indicate that SERS technique has a great potential for rapid, simple, in situ, and cost-effective detection and monitoring of permethrin in environment and on foods.
Published in |
American Journal of Nano Research and Applications (Volume 3, Issue 1-1)
This article belongs to the Special Issue Nanomaterials and Nanosensors for Chemical and Biological Detection |
DOI | 10.11648/j.nano.s.2015030101.16 |
Page(s) | 29-32 |
Creative Commons |
This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited. |
Copyright |
Copyright © The Author(s), 2015. Published by Science Publishing Group |
SERS, Silver Nanofilm, Permethrin, Detection, Portable Raman
[1] | Jeanmaire DL, Van Duyne RP. Surface raman spectroelectrochemistry: Part I. Heterocyclic, aromatic, and aliphatic amines adsorbed on the anodized silver electrode. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry. 1977;84:1-20. |
[2] | Sharma B, Frontiera RR, Henry A-I, Ringe E, Van Duyne RP. SERS: Materials, applications, and the future. Materials Today. 2012;15:16-25. |
[3] | Yan B, Hong Y, Chen T, Reinhard BM. Monitoring enzymatic degradation of pericellular matrices through SERS stamping. Nanoscale. 2012;4:3917-25. |
[4] | Du J, Jing C. Preparation of Thiol Modified Fe3O4@Ag Magnetic SERS Probe for PAHs Detection and Identification. The Journal of Physical Chemistry C. 2011;115:17829-35. |
[5] | Kneipp K, Wang Y, Kneipp H, Perelman LT, Itzkan I, Dasari RR, et al. Single Molecule Detection Using Surface-Enhanced Raman Scattering (SERS). Physical Review Letters. 1997;78:1667. |
[6] | Hao J, Han M-J, Han S, Meng X, Su T-L, Wang QK. SERS Detection of Arsenic in Water: a Critical Review. Journal of Environmental Sciences. 2015:Under Review. |
[7] | Zheng J, Pang S, Labuza TP, He L. Evaluation of surface-enhanced Raman scattering detection using a handheld and a bench-top Raman spectrometer: A comparative study. Talanta. 2014;129:79-85. |
[8] | Hao J, Han M-J, Xu Z, Li J, Meng X. Fabrication and evolution of multilayer silver nanofilms for surface-enhanced Raman scattering sensing of arsenate. Nanoscale Research Letters 2011;6:263. |
[9] | Alvarez-Puebla RA, Liz-Marzán LM. SERS Detection of Small Inorganic Molecules and Ions. Angewandte Chemie International Edition. 2012;51:11214-23. |
[10] | Hao J, Han M-J, Li J, Meng X. Surface modification of silver nanofilms for improved perchlorate detection by surface-enhanced Raman scattering. Journal of Colloid and Interface Science. 2012;377:51-7. |
[11] | Chen C, Hao J, Zhu L, Yao Y, Meng X, Weimer W, et al. Direct two-phase interfacial self-assembly of aligned silver nanowire films for surface enhanced Raman scattering applications. Journal of Materials Chemistry A. 2013;1:13496-501. |
[12] | Halvorson RA, Vikesland PJ. Surface-Enhanced Raman Spectroscopy (SERS) for Environmental Analyses. Environmental Science & Technology. 2010;44:7749-55. |
[13] | Alvarez-Puebla RA, Liz-Marzan LM. Environmental applications of plasmon assisted Raman scattering. Energy & Environmental Science. 2010;3:1011-7. |
[14] | Li D-W, Zhai W-L, Li Y-T, Long Y-T. Recent progress in surface enhanced Raman spectroscopy for the detection of environmental pollutants. Microchim Acta. 2014;181:23-43. |
[15] | Hao J, Han M-J, Meng X, Weimer W, Wang QK. Surface-enhanced Raman scattering of perchlorate on cationic-modified silver nanofilms – Effect of inorganic anions. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 2015;136, Part C:1593-9. |
[16] | He L, Chen T, Labuza TP. Recovery and quantitative detection of thiabendazole on apples using a surface swab capture method followed by surface-enhanced Raman spectroscopy. Food Chemistry. 2014;148:42-6. |
[17] | Li W, Lu B, Sheng A, Yang F, Wang Z. Spectroscopic and theoretical study on inclusion complexation of beta-cyclodextrin with permethrin. Journal of Molecular Structure. 2010;981:194-203. |
[18] | Arayne MS, Sultana N, Hussain F. Validated RP-HPLC method for determination of permethrin in bulk and topical preparations using UV-vis detector. Journal of Chromatographic Science. 2011;49:287-91. |
[19] | Vergun D, Leipold JD. Insect-repelling ACUs now available to all Soldiers. From website: http://wwwarmymil/article/88171/Army_s_new_ACUs_combat_insect_borne_diseases. 2012. |
[20] | Kazemipour M, Noroozian E, Tehrani MS, Mahmoudian M. A new second-derivative spectrophotometric method for the determination of permethrin in shampoo. Journal of Pharmaceutical and Biomedical Analysis 2002;30:1379–84. |
[21] | Shan G, Leeman WR, Stoutamire DW, Gee SJ, Chang DPY, Hammock BD. Enzyme-Linked Immunosorbent Assay for the Pyrethroid Permethrin. Journal of Agricultural and Food Chemistry. 2000;48:4032-40. |
[22] | Baby RE, Cabezas M, Walsöe de Reca EN. Electronic nose: a useful tool for monitoring environmental contamination. Sensors and Actuators B: Chemical. 2000;69:214-8. |
[23] | Ogata-Kawatal H, Matsudal M, Onda N, Ueyama J, Kamijima M, Shibata E, et al. Direct analysis of permethrins in human blood by SPE-GC/MS. Chromatography. 2007;28:119–24. |
[24] | Arip MNM, Heng LY, Ahmad M, Hasbullah SA. Reaction of 2,6-dichloroquinone-4-chloroimide (Gibbs reagent) with permethrin – an optical sensor for rapid detection of permethrin in treated wood. Chemistry Central Journal. 2013;7:122. |
[25] | Han M-J, Hao J, Xu Z, Meng X. Surface-enhanced Raman scattering for arsenate detection on multilayer silver nanofilms. Analytica Chimica Acta. 2011;692:96-102. |
APA Style
Jumin Hao, Qingwu K. Wang, Wayne Weimer, Justin Abell, Monika Wilson. (2015). SERS Spectra of Permethrin on Silver Nanofilm. American Journal of Nano Research and Applications, 3(1-1), 29-32. https://doi.org/10.11648/j.nano.s.2015030101.16
ACS Style
Jumin Hao; Qingwu K. Wang; Wayne Weimer; Justin Abell; Monika Wilson. SERS Spectra of Permethrin on Silver Nanofilm. Am. J. Nano Res. Appl. 2015, 3(1-1), 29-32. doi: 10.11648/j.nano.s.2015030101.16
@article{10.11648/j.nano.s.2015030101.16, author = {Jumin Hao and Qingwu K. Wang and Wayne Weimer and Justin Abell and Monika Wilson}, title = {SERS Spectra of Permethrin on Silver Nanofilm}, journal = {American Journal of Nano Research and Applications}, volume = {3}, number = {1-1}, pages = {29-32}, doi = {10.11648/j.nano.s.2015030101.16}, url = {https://doi.org/10.11648/j.nano.s.2015030101.16}, eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.nano.s.2015030101.16}, abstract = {Surface enhanced Raman scattering (SERS) has emerged as an ultrasensitive analytical tool for chemical, biological, and medical analysis. SERS spectra of permethrin, a common synthetic pyrethroid, were investigated for the first time. The SERS substrates used in this work were a silver nanofilm (AgNF) deposited on glass chips. The characteristic SERS bands of permethrin were analyzed and assigned to the corresponding modes. The strongest SERS band appeared at 1003 cm-1 due to the breath vibration of benzene ring in the permethrin molecule. A detection limit of 10 ppm was obtained on the AgNF sub-strates. A good linear relationship between peak height of the 1003 cm-1 band and permethrin concentration was observed in the range of 10 – 1000 ppm. The results obtained in this work indicate that SERS technique has a great potential for rapid, simple, in situ, and cost-effective detection and monitoring of permethrin in environment and on foods.}, year = {2015} }
TY - JOUR T1 - SERS Spectra of Permethrin on Silver Nanofilm AU - Jumin Hao AU - Qingwu K. Wang AU - Wayne Weimer AU - Justin Abell AU - Monika Wilson Y1 - 2015/04/28 PY - 2015 N1 - https://doi.org/10.11648/j.nano.s.2015030101.16 DO - 10.11648/j.nano.s.2015030101.16 T2 - American Journal of Nano Research and Applications JF - American Journal of Nano Research and Applications JO - American Journal of Nano Research and Applications SP - 29 EP - 32 PB - Science Publishing Group SN - 2575-3738 UR - https://doi.org/10.11648/j.nano.s.2015030101.16 AB - Surface enhanced Raman scattering (SERS) has emerged as an ultrasensitive analytical tool for chemical, biological, and medical analysis. SERS spectra of permethrin, a common synthetic pyrethroid, were investigated for the first time. The SERS substrates used in this work were a silver nanofilm (AgNF) deposited on glass chips. The characteristic SERS bands of permethrin were analyzed and assigned to the corresponding modes. The strongest SERS band appeared at 1003 cm-1 due to the breath vibration of benzene ring in the permethrin molecule. A detection limit of 10 ppm was obtained on the AgNF sub-strates. A good linear relationship between peak height of the 1003 cm-1 band and permethrin concentration was observed in the range of 10 – 1000 ppm. The results obtained in this work indicate that SERS technique has a great potential for rapid, simple, in situ, and cost-effective detection and monitoring of permethrin in environment and on foods. VL - 3 IS - 1-1 ER -