For the first time in hydrochemical conditions tetrathioarsenates of d10-metals by composition Ag3AsS4 and M3(AsS4)2•H2O, where M-Zn, Cd or Hg and X=(Zn) or 2(Cd, Hg), were synthesized. Their composition, constitution, reaction of dehydration and thermal shock resistance in 20-1000 interval were studied by means of thermal analysis, UR-spectroscopy, X-ray crystal determination and derivatographic research.
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Earth Sciences (Volume 4, Issue 5-1)
This article belongs to the Special Issue Modern Problems of Geography and Anthropology |
DOI | 10.11648/j.earth.s.2015040501.25 |
Page(s) | 84-87 |
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Tetrathioarsenate, IR-spectra, X-ray Crystal Determination
[1] | Masson J. Sur les arseniates de stroncium//Compt. rend. 1977, c.285, №12. pp. 389-392. |
[2] | Charles-Messance B., Duc Mauge C., Guerin H. Sur les arseniates de cobalt// Compt. rend. 1960, №3. pp. 2216-2217. |
[3] | Charles-Messance B., Duc Mauge C., Guerin H. Sur les arseniates de nikel// Bull. Soc. Chim. France. 1959. №1. pp. 121. |
[4] | Beilina A.Z., Jumanova K.M., Muldakhmetiov Z.M., Khalitiva R.C. About physical-chemical properties of the main arsenates of copper //J. Physichesko khimii. 1977, v. 51, 2. pp. 480-482. |
[5] | Jumanova K.M., Beilina A.Z., Muldakhmetiov Z.M. Investigation of the nickel arsenate compounds by the IR-spectroscopy, thermographic and roentgen-phase analysis methods. Karaganda, 1977, ВИНИТИ 20.09.77, 3713. |
[6] | Beilina A.Z., Jumanova K.M., Muldakhmetiov Z.M., Sargazina L.J. Investigations of arsenate compounds of copper, nickel, iron, titanium obtained in system M(OH)n-As2O5-H2O//Ximia i texnologia coedinrnii Arsenic and antimony. Alma-Ata, 1980, pp. 80-89. |
[7] | Makhmetov M.J., Sagadieva A.K., Chuprakov V.N. Investigations of solubility of iron arsenate. //J. Prikladnoi Ximii. 1981, v.54. №5, pp. 1009-1011. |
[8] | Stahl-Brasse R., Ariguib-kbir., Guerin H. Contribution a l′etude des arseniates tricalciques et des arseniates des calcium′apatitiques //Bull. Soc. chim. France. 1971. №8. pp. 2828-2832. |
[9] | Rukovodstvo po neorgznicheskomu sintezu. Pod red. G.M. Brower. T.2. Moskvs, 1985, 627 (Russian).Ewins E. //J. Chem. Soc. 1916, №135, pp. 189. |
[10] | Sharlo G. Methods of analytical chemistry. Quantitative analysis of inorganic compounds. M., Ximia. 1966, 975 pp. |
[11] | Gilebrand V.F., Lendel G.E., Brait G.A., Gofman D.I. Practical handbook on inorganic analysis. M., Ximia. 1966, 1111 pp. |
[12] | R.R. Shagidullin, S.V., Izosimova. Izv. AN SSSR. Ser. khim., 5, 1976, 1045-1048. In Russian. |
[13] | K. Nakamoto. Infrakrasnie spectry neorganicheskikh i koordinatsionnykh soedinenii. Moskva. 1966. 411. In Russian. |
APA Style
I. Didbaridze, M. Rusia, K. Rukhaia. (2015). Synthesis and Study of Tetrathioarsenates of d10-Metals. Earth Sciences, 4(5-1), 84-87. https://doi.org/10.11648/j.earth.s.2015040501.25
ACS Style
I. Didbaridze; M. Rusia; K. Rukhaia. Synthesis and Study of Tetrathioarsenates of d10-Metals. Earth Sci. 2015, 4(5-1), 84-87. doi: 10.11648/j.earth.s.2015040501.25
AMA Style
I. Didbaridze, M. Rusia, K. Rukhaia. Synthesis and Study of Tetrathioarsenates of d10-Metals. Earth Sci. 2015;4(5-1):84-87. doi: 10.11648/j.earth.s.2015040501.25
@article{10.11648/j.earth.s.2015040501.25, author = {I. Didbaridze and M. Rusia and K. Rukhaia}, title = {Synthesis and Study of Tetrathioarsenates of d10-Metals}, journal = {Earth Sciences}, volume = {4}, number = {5-1}, pages = {84-87}, doi = {10.11648/j.earth.s.2015040501.25}, url = {https://doi.org/10.11648/j.earth.s.2015040501.25}, eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.earth.s.2015040501.25}, abstract = {For the first time in hydrochemical conditions tetrathioarsenates of d10-metals by composition Ag3AsS4 and M3(AsS4)2•H2O, where M-Zn, Cd or Hg and X=(Zn) or 2(Cd, Hg), were synthesized. Their composition, constitution, reaction of dehydration and thermal shock resistance in 20-1000 interval were studied by means of thermal analysis, UR-spectroscopy, X-ray crystal determination and derivatographic research.}, year = {2015} }
TY - JOUR T1 - Synthesis and Study of Tetrathioarsenates of d10-Metals AU - I. Didbaridze AU - M. Rusia AU - K. Rukhaia Y1 - 2015/07/23 PY - 2015 N1 - https://doi.org/10.11648/j.earth.s.2015040501.25 DO - 10.11648/j.earth.s.2015040501.25 T2 - Earth Sciences JF - Earth Sciences JO - Earth Sciences SP - 84 EP - 87 PB - Science Publishing Group SN - 2328-5982 UR - https://doi.org/10.11648/j.earth.s.2015040501.25 AB - For the first time in hydrochemical conditions tetrathioarsenates of d10-metals by composition Ag3AsS4 and M3(AsS4)2•H2O, where M-Zn, Cd or Hg and X=(Zn) or 2(Cd, Hg), were synthesized. Their composition, constitution, reaction of dehydration and thermal shock resistance in 20-1000 interval were studied by means of thermal analysis, UR-spectroscopy, X-ray crystal determination and derivatographic research. VL - 4 IS - 5-1 ER -